DP Physics · HL · Topic B - The particulate nature of matter

B.4 Thermodynamics (HL only)

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  1. Question 1

    A monatomic ideal gas contains 3.0×1023 particles at a temperature of 400K. What is the internal energy of the gas? (Use kB​=1.38×10−23J K−1)
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    A2.48×103J

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Identify the formula for internal energy

    For a monatomic ideal gas, the internal energy is given by U=23​NkB​T where N is the number of particles, kB​ is the Boltzmann constant, and T is the absolute temperature.

    Step 2: Substitute the given values

    U=23​×(3.0×1023)×(1.38×10−23)×400

    Step 3: Calculate step by step

    First: NkB​=3.0×1023×1.38×10−23=4.14J K−1. Then: U=23​×4.14×400=1.5×1656=2484J≈2.48×103J.

    Step 4: Select the correct answer

    The internal energy is approximately 2.48×103J.

    Method #2Approach 2

    Step 1: Identify the calculation required

    We need U=23​NkB​T. The expected order of magnitude: NkB​≈3×1023×1.4×10−23≈4.2, so U≈1.5×4.2×400≈2520J.

    Step 2: Eliminate $1.66 \times 10^3\,\text{J}$

    This value corresponds to using 21​NkB​T (using a factor of 1 instead of 23​) — this ignores that a monatomic gas has 3 translational degrees of freedom, not 1.

    Step 3: Eliminate $3.31 \times 10^3\,\text{J}$

    This is approximately double the expected value, perhaps from mistakenly using 23​×2×NkB​T. It does not match the correct formula.

    Step 4: Eliminate $4.97 \times 10^3\,\text{J}$

    This is roughly 25​NkB​T, which applies to diatomic (not monatomic) gases. The question specifies a monatomic gas.

    Step 5: Select the correct answer

    Only 2.48×103J matches the correct application of U=23​NkB​T.

  2. Question 2

    A fixed amount of gas undergoes an isovolumetric (isochoric) process. Which of the following correctly describes this process?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    AW=0 and ΔU=Q

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Define an isochoric process

    An isovolumetric (isochoric) process occurs at constant volume: ΔV=0.

    Step 2: Determine work done

    Since W=PΔV and ΔV=0, we have W=0. No work is done because the gas does not expand or compress.

    Step 3: Apply the First Law

    From ΔU=Q−W with W=0: ΔU=Q−0=Q All heat added to the gas goes directly into changing internal energy.

    Step 4: Select the correct answer

    The correct description is W=0 and ΔU=Q.

    Method #2Approach 2

    Step 1: Recall the four process types

    We need to match the correct equations to an isochoric process. The First Law is ΔU=Q−W.

    Step 2: Eliminate '$Q = 0$ and $\Delta U = -W$'

    This describes an adiabatic process, not isochoric. Q=0 means no heat exchange — there is no requirement for this in an isochoric process.

    Step 3: Eliminate '$\Delta U = 0$ and $Q = W$'

    This describes an isothermal process where temperature (and hence internal energy) is constant. An isochoric process can have a changing temperature.

    Step 4: Eliminate '$W = P\Delta V$ and $Q = \Delta U + W$'

    This describes an isobaric process. While Q=ΔU+W is just a rearrangement of the First Law, pairing it with W=PΔV implies ΔV=0, which contradicts constant volume.

    Step 5: Select the correct answer

    Only 'W=0 and ΔU=Q' correctly describes an isochoric process.

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