DP Physics · HL / SL · Topic B - The particulate nature of matter

B.3 Gas laws

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Introduction: Why Do Gases Behave the Way They Do?

Picture yourself inflating a balloon. As you blow air into it, the balloon expands. Inside, air molecules are in constant, random motion , colliding with each other and with the balloon's walls. These collisions create pressure, and as you add more air, the number of collisions per second increases, pushing the walls outward.

This everyday observation is governed by the ideal gas law, a single equation that links four measurable quantities: pressure, volume, temperature, and amount of gas. To truly understand it, though, we also need the kinetic theory of gases , a model that explains macroscopic gas behaviour in terms of the motion of individual molecules.

Analogy

Think of gas molecules like a crowd of people in a room. The more people there are (more moles), the more they bump into the walls. The faster they move (higher temperature), the harder each bump. Together, these factors determine how much the walls are pushed outward , that's pressure.

The Ideal Gas Law

Ideal Gas Law: A fundamental equation of state for an ideal gas: PV=nRT where P is pressure (Pa), V is volume (m³), n is the number of moles, R is the universal gas constant (8.31 J K−1mol−1), and T is absolute temperature (K).

Each variable plays a distinct physical role:

  • Pressure (P): Force per unit area exerted by gas molecules colliding with container walls, measured in Pascals (Pa).
  • Volume (V): The space available for gas molecules to occupy, measured in m³.
  • Temperature (T): A measure of the average kinetic energy of the gas molecules, always in Kelvin (K).
  • Moles (n): The amount of gas; 1 mol=6.022×1023 particles (Avogadro's number).
  • R=8.31 J K−1mol−1: The universal gas constant , the same for all ideal gases.
Warning

Always use absolute temperature in Kelvin when applying the ideal gas law. Convert using: TK​=T°C​+273.15 Forgetting this is one of the most common errors in gas law calculations.

The Ideal Gas Law
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← Previous topicB.2 Greenhouse effectNext topic →B.4 Thermodynamics (HL only)
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