DP Physics · HL / SL · Topic B - The particulate nature of matter

B.1 Thermal energy transfers

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  1. Question 1

    Which of the following best describes what temperature measures at the microscopic level?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    BThe average random kinetic energy of the particles in a substance

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Identify the concept being tested

    The question asks for the microscopic meaning of temperature, which is a fundamental definition in thermal physics.

    Step 2: Recall the microscopic definition

    Temperature is defined as a measure of the average random kinetic energy of the particles in a substance. This is directly expressed in the equation Eˉk​=23​kB​T where T is the absolute temperature.

    Step 3: Distinguish from internal energy

    Temperature does not account for the total energy of a system. Internal energy includes both kinetic and potential energy of all particles. Temperature only reflects the average kinetic component.

    Step 4: Select the correct answer

    The correct answer is 'The average random kinetic energy of the particles in a substance', which precisely matches the microscopic definition of temperature.

    Method #2Approach 2

    Step 1: Identify what the question is asking

    The question asks what temperature measures microscopically — we need to eliminate options that describe other thermal physics concepts.

    Step 2: Eliminate 'The total kinetic and potential energy of all particles'

    This describes internal energy, not temperature. Internal energy sums both kinetic and intermolecular potential energy contributions across all particles, which is a different quantity.

    Step 3: Eliminate 'The rate at which thermal energy is transferred'

    This describes the concept of heat flow or thermal power, not temperature. Temperature is a state property, not a rate of transfer.

    Step 4: Eliminate 'The total number of collisions per unit time'

    Collision frequency is related to particle density and speed, but it is not the definition of temperature. A gas could have many slow collisions at low temperature.

    Step 5: Select the correct answer

    The remaining option, 'The average random kinetic energy of the particles in a substance', correctly defines temperature at the microscopic level.

  2. Question 2

    A sample of helium gas is heated from 27°C to 327°C. By what factor does the average random kinetic energy of a helium atom change?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    AIt doubles

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Identify the relevant equation

    The average random kinetic energy is given by Eˉk​=23​kB​T where T must be in kelvin. Since Eˉk​∝T, the ratio of kinetic energies equals the ratio of absolute temperatures.

    Step 2: Convert temperatures to kelvin

    Initial temperature: T1​=27+273=300 K. Final temperature: T2​=327+273=600 K.

    Step 3: Calculate the ratio

    Eˉk1​Eˉk2​​=T1​T2​​=300600​=2 The average kinetic energy doubles.

    Step 4: State the conclusion

    The average random kinetic energy doubles when the absolute temperature doubles. This illustrates why Celsius temperatures cannot be used directly in this equation.

    Method #2Approach 2

    Step 1: Identify what is being asked

    The question asks for the factor of change in average kinetic energy. The key insight is that Eˉk​∝T (in kelvin), so we must convert temperatures first.

    Step 2: Eliminate 'It stays the same'

    The temperature clearly increases, so from Eˉk​=23​kB​T, the kinetic energy must also increase. This option is incorrect.

    Step 3: Eliminate 'It increases by a factor of 12'

    This would only be true if T changed by a factor of 12. T1​=300 K and T2​=600 K, giving a ratio of 2, not 12.

    Step 4: Eliminate 'It increases by a factor of 4'

    A factor of 4 would require T2​=4×T1​=1200 K. However T2​=600 K, not 1200 K. This answer likely comes from incorrectly using Celsius: 327/27≈12, not 4 either.

    Step 5: Select the correct answer

    Since T2​/T1​=600/300=2, the kinetic energy doubles. The correct answer is 'It doubles'.

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