DP Chemistry · HL / SL · Structure 2. Models of bonding and structure

S2.2 The covalent model

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  1. Question 1

    Which of the following correctly describes how a covalent bond forms between two non-metal atoms?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    BA shared pair of electrons creates electrostatic attraction between the electrons and both nuclei.

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Identify the question focus

    The question asks for the correct description of covalent bond formation between two non-metal atoms.

    Step 2: Recall the definition of a covalent bond

    A covalent bond forms when two non-metal atoms share a pair of electrons. The stability arises from the electrostatic attraction between the shared electron pair and the positively charged nuclei of both bonded atoms.

    Step 3: Identify what is different about the other bond types

    Complete electron transfer describes ionic bonding. A sea of delocalised electrons describes metallic bonding. Sharing of protons does not occur in any standard chemical bond.

    Step 4: Select the correct answer

    The only option consistent with covalent bonding is: "A shared pair of electrons creates electrostatic attraction between the electrons and both nuclei."

    Method #2Approach 2

    Step 1: What is being asked?

    We need to identify the correct description of covalent bond formation specifically between non-metal atoms.

    Step 2: Eliminate: complete electron transfer

    "One atom completely transfers electrons to the other, creating oppositely charged ions" describes ionic bonding, not covalent bonding. Eliminated.

    Step 3: Eliminate: sea of delocalised electrons

    "Positive metal ions held together by a sea of delocalised electrons" describes metallic bonding. Non-metals are involved here, so this is eliminated.

    Step 4: Eliminate: proton sharing

    "Protons are shared between two atomic nuclei" is scientifically incorrect — nuclei do not share protons in any type of chemical bond. Eliminated.

    Step 5: Select the correct answer

    The remaining option — "A shared pair of electrons creates electrostatic attraction between the electrons and both nuclei" — correctly describes covalent bond formation.

  2. Question 2

    Silicon dioxide (SiO2​) is a solid with a very high melting point of 1713°C. It does not conduct electricity in the solid state. Each silicon atom is bonded to four oxygen atoms in a tetrahedral arrangement, forming an extended three-dimensional lattice. Which set of statements about SiO2​ is correct? I. It has a giant covalent (network) structure. II. It is a poor electrical conductor. III. Each silicon atom has a tetrahedral arrangement of bonds.
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    DI, II, and III

    Step-by-step walkthrough

    Choose a solution method

    Method #1Approach 1

    Step 1: Identify the structure of SiO₂

    SiO2​ is a giant covalent (network) structure — a continuous three-dimensional lattice of covalently bonded atoms, similar to diamond. Statement I is therefore correct.

    Step 2: Assess electrical conductivity

    In a giant covalent structure, all electrons are localised in covalent bonds. There are no free-moving charged particles, so SiO2​ is a poor conductor of electricity. Statement II is correct.

    Step 3: Assess bond geometry around silicon

    Silicon has four valence electrons and forms four bonds to oxygen atoms. Using VSEPR: 4 bonding pairs, 0 lone pairs → tetrahedral arrangement (109.5°). Statement III is correct.

    Step 4: Select the correct answer

    All three statements are correct, so the answer is I, II, and III.

    Method #2Approach 2

    Step 1: What is being asked?

    We need to determine which combination of three statements about SiO2​ is entirely correct.

    Step 2: Test Statement I

    The question states SiO2​ forms an extended three-dimensional lattice of covalent bonds — this is the definition of a giant covalent structure. Statement I is correct; options that exclude I ("II and III only") are eliminated.

    Step 3: Test Statement II

    Since all electrons are in localised covalent bonds with no free charge carriers, SiO2​ cannot conduct electricity. Statement II is correct; "I and III only" is eliminated.

    Step 4: Test Statement III

    Silicon forms 4 bonds to oxygen with no lone pairs, giving a tetrahedral geometry (109.5°). Statement III is correct; "I and II only" is eliminated.

    Step 5: Select the correct answer

    All three statements are verified as correct, so the answer is I, II, and III.

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